Time-resolved frequency comb spectroscopy for studying the kinetics and branching ratio of OD+CO

Bui, Thinh Quoc

Permalink

https://hdl.handle.net/2142/91438 Copy

Description

Title

Time-resolved frequency comb spectroscopy for studying the kinetics and branching ratio of OD+CO

Author(s)

Bui, Thinh Quoc

Contributor(s)

• Ye, Jun
• Okumura, Mitchio
• Spaun, Ben
• Changala, Bryan
• Heckl, Oliver H.
• Bjork, Bryce J.

Issue Date

2016-06-21

Keyword(s)

Spectroscopy in Atmospheric Chemistry

Abstract

The chemical kinetics of the OH+CO reaction plays important roles in combustion and atmospheric processes. OH+CO has two product channels, H+CO$_2$ and the stabilized HOCO intermediate, with a branching ratio that is highly pressure dependent. Therefore, establishing an accurate kinetic model for this chemical system requires knowledge of the reaction rates and product yields, and the lifetimes of all molecules along a particular reaction pathway. We report the application of time-resolved frequency comb spectroscopy (TRFCS) in the mid-infrared (3.7 $\mu$m) spectral region to address the complex reaction kinetics of OD+CO at room temperature. We use the deuterated forms to avoid atmospheric water interference. This technique allows us to detect the lowest energy conformer trans-DOCO intermediate with high time-resolution and sensitivity while also permitting the direct determination of rotational state distributions of all relevant molecules. We simultaneously observe the time-dependent concentrations of trans-DOCO, OD, and D$_2$O which are used in conjunction with kinetics modeling to obtain the pressure- and collision partner-dependent branching ratio of OD+CO.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

text

Language

En

Permalink

http://hdl.handle.net/2142/91438

Copyright and License Information

Copyright 2016 by the authors

Owning Collections