Determination of the preferred structure, dynamics, and planarity of substituted anhydrides by cp-ftmw
Bird, Ryan G.
Loading…
Permalink
https://hdl.handle.net/2142/91297
Description
Title
Determination of the preferred structure, dynamics, and planarity of substituted anhydrides by cp-ftmw
Author(s)
Bird, Ryan G.
Contributor(s)
Pratt, David
Bailey, Josiah R.
McMahon, Timothy J.
Issue Date
2016-06-20
Keyword(s)
Structure determination
Abstract
The planarity of five-membered rings is derived from a competition between ring-angle strain and stability of the torsional angles. The planar form maximizes the already stressed, smaller-than-normal, C-C bond angles, while puckering reduces the unfavorable eclipsed interactions. The structure, dynamics, and planarity of three anhydrides, succinic, methylsuccinic, and methylene (itaconic) anhydride, were studied and compared using chirped-pulse Fourier transform microwave spectroscopy.
Use this login method if you
don't
have an
@illinois.edu
email address.
(Oops, I do have one)
IDEALS migrated to a new platform on June 23, 2022. If you created
your account prior to this date, you will have to reset your password
using the forgot-password link below.
