Structures and solvation effects of [Fe(CO2)n]− cluster anions

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https://hdl.handle.net/2142/91131

Title: Structures and solvation effects of [Fe(CO2)n]− cluster anions
Author(s): Thompson, Michael C.
Contributor(s): Weber, J. Mathias
Issue Date: 2016-06-22
Keyword(s): Clusters/Complexes
Date of Ingest: 2017-01-26T21:38:35Z
Abstract: We present infrared photodissociation spectra of [Fe(\chem{CO_2})$_{n}$]$^{-}$ ($n=3-7$) cluster anions. We use density functional theory to compare calculated vibrational frequencies to our experimental spectra to determine plausible structures for the molecular charge carriers. The spectra display similar characteristics to those of other complexes of first-row transition metals with \chem{CO_2} ligands, and show signatures of several structural motifs.
Publisher: International Symposium on Molecular Spectroscopy
Type of Resource: text
Genre of Resource: Conference Paper / Presentation
Language: En
Permalink: http://hdl.handle.net/2142/91131