Structures and solvation effects of [Fe(CO2)n]− cluster anions
Thompson, Michael C.
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https://hdl.handle.net/2142/91131
Description
Title
Structures and solvation effects of [Fe(CO2)n]− cluster anions
Author(s)
Thompson, Michael C.
Contributor(s)
Weber, J. Mathias
Issue Date
2016-06-22
Keyword(s)
Clusters/Complexes
Abstract
We present infrared photodissociation spectra of [Fe(\chem{CO_2})$_{n}$]$^{-}$ ($n=3-7$) cluster anions. We use density functional theory to compare calculated vibrational frequencies to our experimental spectra to determine plausible structures for the molecular charge carriers. The spectra display similar characteristics to those of other complexes of first-row transition metals with \chem{CO_2} ligands, and show signatures of several structural motifs.
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