Microwave observation of the van der waals complex O2-CO
Grubbs, G.S., II
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https://hdl.handle.net/2142/91451
Description
Title
Microwave observation of the van der waals complex O2-CO
Author(s)
Grubbs, G.S., II
Contributor(s)
Dawes, Richard
Ndengue, Steve Alexandre
Moon, Nicole
Gillcrist, David Joseph
Persinger, Thomas D.
Marshall, Frank E.
Issue Date
2016-06-22
Keyword(s)
Clusters/Complexes
Abstract
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FTMW spectroscopy has long been known to be a powerful tool in characterizing van der Waals complexes.\footnote{Stewart Novick, \textit{Bibliography of Rotational Spectra of Weakly Bound Complexes}} Along with this, advances in microwave technology and computing have made complicated spin-interaction systems much easier to observe and characterize. One such system, O$_2$-CO has been observed for the first time on a CP-FTMW spectrometer operational in the 6-18 GHz region. Preliminary observations and calculations indicate a slipped-parallel structure. High level calculations are ongoing, including the construction of a 4D potential energy surface. Rotational assignments, along with any observed fine structure due to the $^3\Sigma$ ground state of O$_2$ will be discussed.
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