CP-FTMW spectrum of bromoperfluoroacetone

Marshall, Frank E.

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https://hdl.handle.net/2142/91474 Copy

Description

Title

CP-FTMW spectrum of bromoperfluoroacetone

Author(s)

Marshall, Frank E.

Contributor(s)

• Grubbs II, G. S.
• Gillcrist, David Joseph
• Persinger, Thomas D.
• Moon, Nicole

Issue Date

2016-06-22

Keyword(s)

(Hyper)fine structure, tunneling

Date of Ingest

2017-01-26T21:37:57Z

Abstract

The microwave spectrum of the molecule bromoperfluoroacetone has been measured on a CP-FTMW spectrometer in the 6-18. The spectra is dense with approximately one transition every 5 MHz on average. Rotational constants, centrifugal distortion parameters, and nuclear quadrupole coupling constants will be discussed. Comparisons to the previously studied halogen analogues perfluoroacetone\footnote{J.-U. Grabow, N. Heineking, and W. Stahl, \textit{Z. Naturforsch.} \textbf{46a} (1991) 229.} and chloroperfluoroacetone\footnote{G. Kadiwar, C. T. Dewberry, G. S. Grubbs II and S. A. Cooke, Talk \textbf{RH11}, 65$^{\mathrm{th}}$ International Symposium on Molecular Spectroscopy (2010).} along with a family of previously studied halogenated acetone species will be discussed.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

text

Genre of Resource

Conference Paper / Presentation

Language

En

Permalink

http://hdl.handle.net/2142/91474

Copyright and License Information

Copyright 2016 by the authors

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