Highly unsaturated platinum and palladium carbenes ptC3 and pdC3 isolated and characterized in the gas phase
Walker, Nick
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https://hdl.handle.net/2142/91194
Description
Title
Highly unsaturated platinum and palladium carbenes ptC3 and pdC3 isolated and characterized in the gas phase
Author(s)
Walker, Nick
Contributor(s)
Legon, Anthony
Tew, David Peter
Zaleski, Daniel P.
Bittner, Dror M.
Issue Date
2016-06-23
Keyword(s)
Metal containing
Abstract
Carbenes of platinum and palladium, \chem{PtC_3} and \chem{PdC_3}, were generated in the gas phase through laser vaporization of a metal target in the presence of a low concentration of a hydrocarbon precursor undergoing supersonic expansion. Rotational spectroscopy and \textit{ab initio} calculations confirm that both molecules are linear. The geometry of \chem{PtC_3} was accurately determined by fitting to the experimental moments of inertia of twenty-six isotopologues.
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