University of Illinois Urbana-Champaign

VELOCITY MAP IMAGING STUDY OF THE PHOTOINITIATED CHARGE-TRANSFER DISSOCIATION OF Cu+(C6H6) AND Ag+(C6H6)

Maner, Jon

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1272.pdf
466824.pptx

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https://hdl.handle.net/2142/79348

Description

Title
VELOCITY MAP IMAGING STUDY OF THE PHOTOINITIATED CHARGE-TRANSFER DISSOCIATION OF Cu+(C6H6) AND Ag+(C6H6)
Author(s)
Maner, Jon
Contributor(s)
  • Duncan, Michael A.
  • Mauney, Daniel
Issue Date
25-Jun-15
Keyword(s)
Instrument/Technique Demonstration
Date of Ingest
2016-01-05T20:07:19Z
Abstract
M$^{+}$(C$_{6}$H$_{6}$) (M = Cu, Ag) complexes are generated in the gas phase by laser vaporization and detected in a reflectron time-of-flight mass spectrometer. Excitation of M$^{+}$(C$_{6}$H$_{6}$) at 355 nm results exclusively in dissociative charge transfer, leading to neutral M and C$_{6}$H$_{6}$$^{+}$ products for both Cu and Ag complexes. Kinetic energy release in translationally hot C$_{6}$H$_{6}$$^{+}$ fragments is detected using a new apparatus designed for photofragment imaging of mass-selected ion beams. Velocity map imaging and slice imaging techniques are employed. Analysis of the data provide new information on the binding energies of Cu$^{+}$(C$_{6}$H$_{6}$) and Ag$^{+}$(C$_{6}$H$_{6}$).
Publisher
International Symposium on Molecular Spectroscopy
Type of Resource
text
Genre of Resource
Conference Paper / Presentation
Language
English
Permalink
http://hdl.handle.net/2142/79348

Owning Collections

Abstracts & Presentations - 2015 International Symposium on Molecular Spectroscopy PRIMARY