THE NEAR-INFRARED SPECTRUM OF NiCl: ANALYSES OF THE (0,1), (1,0), & (2,1) BANDS OF SYSTEM G AND THE (1,0) BAND OF SYSTEM H

Harms, Jack C.

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https://hdl.handle.net/2142/79214 Copy

Description

Title

THE NEAR-INFRARED SPECTRUM OF NiCl: ANALYSES OF THE (0,1), (1,0), & (2,1) BANDS OF SYSTEM G AND THE (1,0) BAND OF SYSTEM H

Author(s)

Harms, Jack C.

Contributor(s)

• O'Brien, Leah C.
• O'Brien, James J.
• Grames, Ethan M.
• Gipson, Courtney N

Issue Date

22-Jun-15

Keyword(s)

Small molecules

Abstract

The near-infrared spectrum of nickel chloride, NiCl, has been recorded at high resolution using intracavity laser absorption spectroscopy. The NiCl molecules were produced in a plasma discharge of a nickel hollow cathode from a trace amount of chem{CCl_4} using Ar as the sputter gas. Spectra were collected from 12,490-12,660 wn and 13,200-13,350 wn as a series of overlapping ~5 wn scans. The (0,1), (1,0), and (2,1) bands of the [13.0] $^{2}Pi_{3/2}$-X $^{2}Pi_{3/2}$ transition, System G, were observed at 12,537 wn, 13,352 wn, and 13,318 wn, respectively. The (1,0) band of the [12.3] $^{2}Sigma^{-}$-X $^{2}Pi_{3/2}$ transition, System H, was observed at 12,645 wn. Analyses of these bands will be presented.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

text

Language

English

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http://hdl.handle.net/2142/79214

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