University of Illinois Urbana-Champaign

CAPTURE AND STRUCTURAL DETERMINATION OF ACTIVATED INTERMEDIATES IN NICKEL CATALYZED CO2 REDUCTION

Craig, Stephanie

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1293.pdf
474531.pptx

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https://hdl.handle.net/2142/79371

Description

Title
CAPTURE AND STRUCTURAL DETERMINATION OF ACTIVATED INTERMEDIATES IN NICKEL CATALYZED CO2 REDUCTION
Author(s)
Craig, Stephanie
Contributor(s)
  • Johnson, Mark
  • Tﾚtsch, Niklas
  • Fournier, Joseph
  • Wolk, Arron
  • Menges, Fabian
Issue Date
22-Jun-15
Keyword(s)
Ions
Date of Ingest
2016-01-05T20:06:38Z
Abstract
The catalyzed reduction of CO$_{2}$ is an important step in the conversion of this small molecule into liquid fuels. Nickel 1,4,8,11-tetraazacyclotetradecane, Ni(cyclam), is a well-known catalyst for the reduction of CO$_{2}$ in solution. Cryogenic ion vibrational predissociation (CIVP) spectroscopy of CO$_{2}$-messenger tagged ions cooled in a temperature controlled ion trap was used to study the starting Ni$^{2+}$(cyclam) reactant, and possible reaction intermediates and products in the gas phase. Additionally, parental CO$_{2}$ reduction was observed on the Ni(I) species [Ni(bipyridine-(NMe)$_{2}$)]$_{2}$(diphenyldiacetylene).
Publisher
International Symposium on Molecular Spectroscopy
Type of Resource
text
Genre of Resource
Conference Paper / Presentation
Language
English
Permalink
http://hdl.handle.net/2142/79371

Owning Collections

Abstracts & Presentations - 2015 International Symposium on Molecular Spectroscopy PRIMARY