THE SOLEIL VIEW ON SULFUR RICH OXIDES: THE
_3 MODE OF S2O REVISITED
Thorwirth, Sven
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https://hdl.handle.net/2142/79282
Description
Title
THE SOLEIL VIEW ON SULFUR RICH OXIDES: THE
_3 MODE OF S2O REVISITED
Author(s)
Thorwirth, Sven
Contributor(s)
McCarthy, Michael C.
Schlemmer, Stephan
Lewen, Frank
Gruet, Sébastien
Pirali, Olivier
van Wijngaarden, Jennifer
Salomon, T.
Zingsheim, Oliver
Endres, Christian
Martin-Drumel, Marie-Aline
Issue Date
25-Jun-15
Keyword(s)
Mini-symposium: Accelerator-Based Spectroscopy
Abstract
In the course of our recent study of the $nu_2$ bending mode of S$_2$O (Martin-Drumel el al.; see Talk P1190),
the S-S stretching mode $nu_3$ located at 679cm$^{-1}$ and first studied
by Lindenmayer textit{et al.} in 1986 (textit{J. Mol. Spectrosc.} textbf{119}, 56)
has been re-investigated at the French national synchrotron facility SOLEIL using Fourier-transform far-infrared spectroscopy.
In addition to the vibrational fundamental, evidence for at least one more hot band, most likely $nu_3+nu_2-nu_2$,
was found. Complementary submillimeter wave measurements of the pure rotational
spectrum in the $v_3=1$ state were also performed.
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