LASER SPECTROSCOPY OF THE PHOTOASSOCIATION OF Rb-Ar AND Rb-Kr THERMAL PAIRS: STRUCTURE OF THE Rb-RARE GAS A2_1/2 STATE NEAR THE CLASSICAL LIMIT
Goldshlag, William
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https://hdl.handle.net/2142/79402
Description
Title
LASER SPECTROSCOPY OF THE PHOTOASSOCIATION OF Rb-Ar AND Rb-Kr THERMAL PAIRS: STRUCTURE OF THE Rb-RARE GAS A2_1/2 STATE NEAR THE CLASSICAL LIMIT
Author(s)
Goldshlag, William
Contributor(s)
Eden, J. Gary
Raymond, Kyle T
Mironov, Andrey E.
Issue Date
22-Jun-15
Keyword(s)
Small molecules
Abstract
A new laser spectroscopic technique has been demonstrated for examining the structure of alkali--rare gas diatomic electronic states near the classical limit. In two-color experiments, Rb--Ar or Rb--Kr thermal pairs are excited by free$leftarrow$free or bound$leftarrow$free transitions while monitoring the amplified spontaneous emission produced on the Rb D$_1$ or D$_2$ lines. Spectra observed lying within 10 cm$^{-1}$ of the separated atom limit for the A$^{2}Pi_{1/2}$ states of Rb--Ar and Rb--Kr will be presented and discussed.
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