Rhenium Carbido Carbonyl Cluster Complexes With Group 12 Metal Centers
Wright, Chris Aaron
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Permalink
https://hdl.handle.net/2142/84503
Description
Title
Rhenium Carbido Carbonyl Cluster Complexes With Group 12 Metal Centers
Author(s)
Wright, Chris Aaron
Issue Date
2000
Doctoral Committee Chair(s)
Shapley, John R.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Engineering, Materials Science
Language
eng
Abstract
Exploration of mercury capped rhenium carbido carbonyl clusters as potential labeling agents was initiated. The reaction of [PPh4]2[Re 7C(CO)21HgCl] with L-cysteine in aqueous acetone formed the complex [PPh4]2[Re7C(CO)21HgSCH 2CH(NH3)CO2]. In order to explore further reactions in aqueous solution, work was carried out with [Na]2[Re7C(CO) 21HgCl]. Preliminary work indicates that this complex has potential as an electron dense, easily detectable label for sulfhydryl sites in proteins.
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