University of Illinois Urbana-Champaign

An Organometallic Approach to Iron Triazacyclononane Coordination Complexes

Moreland, Andrew Colby

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Description

Title
An Organometallic Approach to Iron Triazacyclononane Coordination Complexes
Author(s)
Moreland, Andrew Colby
Issue Date
2000
Doctoral Committee Chair(s)
Rauchfuss, Thomas B.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Inorganic
Language
eng
Abstract
The active site of NiFe hydrogenase features a bis(thiolate) bridged nickel-iron site, where the iron is bound to two carbonyls and a cyanide. The reaction of the square planar Ni(N2S2), where (N2S2)2- = -SCH2CH2N(Me)CH2CH 2N(Me)CH2CH2S- and (Me 3TACN)FeCl2 gives [Ni(N2S2)FeCl(Me3TACN)](BPh 4), a complex with a bis(thiolate) bridge between nickel and iron. The reactivity of this complex with CN- and CO was explored.
Graduation Semester
2000
Type of Resource
text
Permalink
http://hdl.handle.net/2142/84489

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