University of Illinois Urbana-Champaign

Binuclear Transition Metal Derivatives of 1,2-Bis(indenyl)ethane

Khayatpoor, Ramin

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Description

Title
Binuclear Transition Metal Derivatives of 1,2-Bis(indenyl)ethane
Author(s)
Khayatpoor, Ramin
Issue Date
2000
Doctoral Committee Chair(s)
Shapley, John R.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Inorganic
Language
eng
Abstract
Heating Ru3(CO)12 with 1,2-bis(indenyl)ethane in xylene provided the binuclear compounds Ru2(CO)4(mu-(eta 5-C9H6)2C2H4 and [(eta5-C9H6)C2H 4(C9H7)Ru(CO)2]2. The corresponding reaction in heptane gave instead the tetranuclear cluster [Ru4H(CO) 9(mu3-eta2-eta2-eta 5-C9H6)](C2H4)(C 9H7). The structure of the rac form of Ru 2(CO)4(mu-(eta5-C9H6) 2C2H4 was determined by x-ray crystallography.
Graduation Semester
2000
Type of Resource
text
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http://hdl.handle.net/2142/84484

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