Ketone -Catalyzed Epoxidation of Alkenes With Oxone and Palladium -Catalyzed Biaryl Synthesis via Silacyclobutanes
Wu, Zhicai
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https://hdl.handle.net/2142/84470
Description
Title
Ketone -Catalyzed Epoxidation of Alkenes With Oxone and Palladium -Catalyzed Biaryl Synthesis via Silacyclobutanes
Author(s)
Wu, Zhicai
Issue Date
2000
Doctoral Committee Chair(s)
Denmark, Scott E.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Organic
Language
eng
Abstract
Aryl(fluoro)silacyclobutanes and aryl(chloro)silacyclobutanes have been found to undergo cross-coupling reactions with aryl iodides. The rate of reaction and extent of homocoupling were dramatically affected by the addition of ligands for the palladium catalyst. A wide range of electronically different and structurally diverse unsymmetrical biaryls have been prepared in good to excellent yields.
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