Molecule-Based Magnets Constructed From Hexacyanometalates

Holmes, Stephen Michael

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Description

Title

Molecule-Based Magnets Constructed From Hexacyanometalates

Author(s)

Holmes, Stephen Michael

Issue Date

2000

Doctoral Committee Chair(s)

Girolami, G.S.

Department of Study

Chemistry

Discipline

Chemistry

Degree Granting Institution

University of Illinois at Urbana-Champaign

Degree Name

Ph.D.

Degree Level

Dissertation

Keyword(s)

Physics, Electricity and Magnetism

Language

eng

Abstract

Improved preparations are given for several first-row transition metal trifluoromethanesulfonate (OTf) and p-toluenesulfonate (OTs) salts: M(OTf)x, where M = VII, VIII, CrII, MnII, CoII, NiII , and Cs, and [M(OH2)n][OTs]x, where M = TiIII, VIII, VIVO, Cr II, CrIII, MnII, FeII, CoII, NiII, and Cs. Also described are preparations of the cyanide building blocks K4[V(CN)6]·xH 2O, [NEt4]4[V(CN)6], K3[Cr(CN) 6]·xH2O, [NEt4]3[Cr(CN) 6]·xH2O, [NEt4]3[Ti(CN) 6]·2.5H2O, [PPN]3[Cr(CN)6], [PPN]3[Fe(CN)6], [NEt4]3[Co(CN) 6]·H2O, [PPN]3[Cr(CN)5NO], [NEt 4]CN, and [PPN]CN.

Graduation Semester

2000

Type of Resource

text

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