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https://hdl.handle.net/2142/84444
Description
Title
The Reactivity of Tetrathioperrhenate
Author(s)
Goodman, Jonathan T.
Issue Date
1999
Doctoral Committee Chair(s)
Rauchfuss, Thomas B.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Inorganic
Language
eng
Abstract
The reaction of ReS4- with nitriles in the presence of S8 yielded azadithiolene (S2NCR 2-) complexes, ReS(S4)(S2NCR)- (R = C6H5, 4-C6H4CF 4, 4-C6H4CO2Me, or 4-C6H 4NO2). The reaction of ReS4- with CF3CN in the presence of 1/8 equiv of S8 yielded ReS(S2NCCF3)2-, in the presence of Me3NO this reaction yielded cis and trans isomers of ReO(S2NCCF3)2-. The trifluoroacetonitrile adduct cis-ReO(S2NCCF 3)2- was crystallographically characterized.
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