Design and Construction of Organic Solids for Second-Order Nonlinear Optics and Nanoporosity
Zhang, Peng
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https://hdl.handle.net/2142/84441
Description
Title
Design and Construction of Organic Solids for Second-Order Nonlinear Optics and Nanoporosity
Author(s)
Zhang, Peng
Issue Date
1999
Doctoral Committee Chair(s)
Moore, Jeffrey S.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Polymer
Language
eng
Abstract
In the second part of this thesis, coordination networks based on silver(I) triflate and tetrahedral ligands functionalized with nitrile groups were found to be porous. Moreover, triflate as a coordinating counterion can be utilized as a mean to increase the predictability of the network structures. Counterion effect was further tested by the crystal structures of silver(I) 3- and 4-cyanobenzenesulfonates which are one- and two-dimensional continuous networks respectively. Finally, phenyl acetylene macrocycle functionalized with nitrile groups and longer tetrahedral ligands were synthesized and the crystallization with silver(I) salts were attempted.
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