University of Illinois Urbana-Champaign

The Role of Hydrogen Bonding in Alkali Metal Ion Solvation

Weinheimer, Corey James

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Description

Title
The Role of Hydrogen Bonding in Alkali Metal Ion Solvation
Author(s)
Weinheimer, Corey James
Issue Date
1998
Doctoral Committee Chair(s)
Lisy, James M.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Physical
Language
eng
Abstract
In addition to the experimental measurements, RRKM/Evaporative ensemble calculations were performed on $\rm Na\sp+(CH\sb3OH)\sb{1-9}$ ion clusters to determine the internal energy distributions of the ion clusters in the ion beam as a function of cluster size. It was found that the vibrational temperatures of $\rm Na\sp+(CH\sb3OH)\sb{m}$ ion clusters ranged from 1066 K for m = 1 to 178 K for m = 9 under experimental conditions.
Graduation Semester
1998
Type of Resource
text
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http://hdl.handle.net/2142/84417

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Dissertations and Theses - Chemistry