University of Illinois Urbana-Champaign

Synthesis and Reactivity of Trimethylsilylthiolate Compounds: Precursors for Heterometallic Complexes

Liang, Hong-Chang

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Description

Title
Synthesis and Reactivity of Trimethylsilylthiolate Compounds: Precursors for Heterometallic Complexes
Author(s)
Liang, Hong-Chang
Issue Date
1997
Doctoral Committee Chair(s)
Shapley, Patricia A.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Inorganic
Language
eng
Abstract
Chapter 4. The synthesis and reactivity of several ruthenium(VI) and osmium(VI) sulfido complexes are reported. The triruthenium sulfido complexes (PPh$\sb4$) ($\rm\{Ru(N)R\sb2\}\sb3(\mu\sb3$-S)$\sb2\rbrack,$ (19, R = Me; 20, R = $\rm CH\sb2SiMe\sb3)$ react with $\rm MeOSO\sb2CF\sb3$ to form $\mu\sb3$-thiolate complexes $\rm\{Ru(N)R\sb2\}\sb3(\mu\sb3$-SMe)($\mu\sb3$-S) (22, R = $\rm CH\sb2SiMe\sb3$; 23, R = Me). Complex 19 reacts with ($\rm Cu(PPh\sb3)\sb2(NCMe)\sb2\rbrack\lbrack BF\sb4\rbrack$ to form ($\rm Cu(PPh\sb3)\sb2\rbrack\lbrack\{Ru(N)R\sb2\}\sb3(\mu\sb3$-S)$\sb2\rbrack,$ 24.
Graduation Semester
1997
Type of Resource
text
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http://hdl.handle.net/2142/84384

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