Hydrocarbon Ligand Derivatives of the Dicarbido Decaruthenium and Related Cluster Frameworks
Lee, Kwangyeol
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https://hdl.handle.net/2142/84383
Description
Title
Hydrocarbon Ligand Derivatives of the Dicarbido Decaruthenium and Related Cluster Frameworks
Author(s)
Lee, Kwangyeol
Issue Date
1997
Doctoral Committee Chair(s)
Shapley, John R.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Inorganic
Language
eng
Abstract
Thermal reaction of $\rm \lbrack Ru\sb{10}C\sb2(CO)\sb{24}\rbrack\sp{2-}$ with C$\sb{60}$ forms $\rm \lbrack Ru\sb{10}C\sb2(CO)\sb{22}(C\sb{60})\rbrack\sp{2-},$ in which the C$\sb{60}$ ligand bridges two apical ruthenium atoms in the $\mu$-$\eta\sp2{:}\eta\sp2$ bonding mode.
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