Coordination Networks of Ditopic Ligands and silver(I) Salts: A Study of Factors Influencing Network Topology
Hirsch, Keith Aaron
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https://hdl.handle.net/2142/84380
Description
Title
Coordination Networks of Ditopic Ligands and silver(I) Salts: A Study of Factors Influencing Network Topology
Author(s)
Hirsch, Keith Aaron
Issue Date
1997
Doctoral Committee Chair(s)
Moore, Jeffrey S.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Organic
Language
eng
Abstract
Aggregation of 2,2$\sp\prime$-, 2,3$\sp\prime$-, and 2,4$\sp\prime$-dicyanodiphenylacetylene with silver(I) has been studied both in solution and the solid state. Solid-state topology is found to depend on the geometry of the ligand. The distribution of aggregates in solution, as determined by electrospray ionization mass spectrometry, also depends on the ligand structure. From this data, the structures of key aggregates observed in solution are proposed.
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