The Development of New Methods for the Introduction of a Vinyl Unit Using Silicon-Based Cross -Coupling Reactions
Butler, Christopher
This item is only available for download by members of the University of Illinois community. Students, faculty, and staff at the U of I may log in with your NetID and password to view the item. If you are trying to access an Illinois-restricted dissertation or thesis, you can request a copy through your library's Inter-Library Loan office or purchase a copy directly from ProQuest.
Permalink
https://hdl.handle.net/2142/84332
Description
Title
The Development of New Methods for the Introduction of a Vinyl Unit Using Silicon-Based Cross -Coupling Reactions
Author(s)
Butler, Christopher
Issue Date
2009
Doctoral Committee Chair(s)
Denmark, Scott E.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Organic
Language
eng
Abstract
"Two unsymmetrical, differentially substituted 1,2-bissilylethylene reagents were prepared and subsequently examined in sequential cross-coupling reactions. These reagents successfully react in the first coupling with aryl iodides and an electron-deficient alkenyl iodide under ""fluoride-free"" conditions. The second, fluoride-activated cross-coupling was explored."
Use this login method if you
don't
have an
@illinois.edu
email address.
(Oops, I do have one)
IDEALS migrated to a new platform on June 23, 2022. If you created
your account prior to this date, you will have to reset your password
using the forgot-password link below.
