University of Illinois Urbana-Champaign

I. Efforts Toward the Total Synthesis of the Stemofoline Alkaloids II. Preliminary Development of a Method to Prepare 1,2-Cis-2-Acetamido-2-Deoxyglycopyranoses

Carra, Ryan

This item is only available for download by members of the University of Illinois community. Students, faculty, and staff at the U of I may log in with your NetID and password to view the item. If you are trying to access an Illinois-restricted dissertation or thesis, you can request a copy through your library's Inter-Library Loan office or purchase a copy directly from ProQuest.

Permalink

https://hdl.handle.net/2142/84303

Description

Title
I. Efforts Toward the Total Synthesis of the Stemofoline Alkaloids II. Preliminary Development of a Method to Prepare 1,2-Cis-2-Acetamido-2-Deoxyglycopyranoses
Author(s)
Carra, Ryan
Issue Date
2008
Doctoral Committee Chair(s)
Gin, David Y.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Organic
Language
eng
Abstract
Efforts to prepare the stemofoline alkaloids via total synthesis are described. Each strategy which is presented utilized a [3+2] cycloaddition of a non-stabilized azomethine ylide as a key step. These studies culminated in the first non-racemic synthesis of the fully-oxygenated tricyclic core of the stemofoline alkaloids. Furthermore, a novel synthetic method to prepare alpha-linked C2-acetamido glycoconjugates is described and preliminary results are presented.
Graduation Semester
2008
Type of Resource
text
Permalink
http://hdl.handle.net/2142/84303

Owning Collections

Graduate Dissertations and Theses at Illinois PRIMARY
Graduate Theses and Dissertations at Illinois
Dissertations and Theses - Chemistry