Palladium-Catalyzed Cross-Coupling Reactions of Heteroaryldimethylsilanols: New Methods for the Formation of Substituted Heterocycles Using Preformed and Isolated Silanolates
Baird, John D.
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https://hdl.handle.net/2142/84299
Description
Title
Palladium-Catalyzed Cross-Coupling Reactions of Heteroaryldimethylsilanols: New Methods for the Formation of Substituted Heterocycles Using Preformed and Isolated Silanolates
Author(s)
Baird, John D.
Issue Date
2008
Doctoral Committee Chair(s)
Scott Denmark
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Organic
Language
eng
Abstract
A procedure for the preparation of multi-substituted indoles using the Larock indole synthesis was developed. The heteroannulation reaction can be used to prepare 2,3-disubstituted indoles in good yields. The identification of a t-butoxysilyl ether as the masked silanol further expanded the scope of this reaction.
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