Part I. Supramolecular Star Polymers Based on Ditopic Hydrogen-Bonding Modules. Part II. The Concept of Fidelity as a Framework for Evaluating the Behavior of Complex Supramolecular Systems
Todd, Eric
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Permalink
https://hdl.handle.net/2142/84288
Description
Title
Part I. Supramolecular Star Polymers Based on Ditopic Hydrogen-Bonding Modules. Part II. The Concept of Fidelity as a Framework for Evaluating the Behavior of Complex Supramolecular Systems
Author(s)
Todd, Eric
Issue Date
2007
Doctoral Committee Chair(s)
Zimmerman, Steven C.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Polymer
Language
eng
Abstract
There is currently no common framework to discuss the quality of these more complex multi-component recognition systems. Part 2 of this dissertation reports undesired, cross-recognition in several commonly used triply and quadruply hydrogen-bonded complexes to assess the likelihood of orthogonal recognition. Modeling of the equilibria in several multi-component systems allows us to introduce a framework for discussing fidelity and the requirements for producing complex supramolecular systems capable of programmed self assembly.
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