Synthesis and Characterization of Organometallic Compounds for Materials
Noh, Wontae
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Permalink
https://hdl.handle.net/2142/84276
Description
Title
Synthesis and Characterization of Organometallic Compounds for Materials
Author(s)
Noh, Wontae
Issue Date
2007
Doctoral Committee Chair(s)
Girolami, Gregory S.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Inorganic
Language
eng
Abstract
A series of BH3PR2BH3- (R =H, Ph, t-Bu) were synthesized and characterized. Treatment of the adduct PH3·BH3 with excess NaBH4 in THF afforded a white powder, Na(BH3PH2BH 3). Reactions of Na(BH3PH2BH3) and Li(BH3PPh2BH3)·diox with several metal halides were described.
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