Studies on the Silanol-Based Cross-Coupling Reaction: (1) Development of Methods for the Synthesis of Aryl and Heteroaryldimethysilanols, (2) Expansion of the Substrate Scope of the Cross-Coupling Reaction and (3) Investigations on the Transmetalation of Organosilanols to Transition Metals
Kallemeyn, Jeffrey M.
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https://hdl.handle.net/2142/84259
Description
Title
Studies on the Silanol-Based Cross-Coupling Reaction: (1) Development of Methods for the Synthesis of Aryl and Heteroaryldimethysilanols, (2) Expansion of the Substrate Scope of the Cross-Coupling Reaction and (3) Investigations on the Transmetalation of Organosilanols to Transition Metals
Author(s)
Kallemeyn, Jeffrey M.
Issue Date
2007
Doctoral Committee Chair(s)
Denmark, Scott E.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Organic
Language
eng
Abstract
To further illuminate the mechanism of transmetalation of alkenyldimethylsilanols a number of molecular traps have been designed, synthesized and subjected to the cross-coupling reaction. A clear preference for formation of the cross-coupling products was observed in these investigations.
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