Part I. DNA Base and Base Analogue Pairing in Organic Solvents. Part II. Ring Closing Metathesis of Poly-Allylated Glycerol Dendrimers
Quinn, Jordan R.
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https://hdl.handle.net/2142/84232
Description
Title
Part I. DNA Base and Base Analogue Pairing in Organic Solvents. Part II. Ring Closing Metathesis of Poly-Allylated Glycerol Dendrimers
Author(s)
Quinn, Jordan R.
Issue Date
2006
Doctoral Committee Chair(s)
Zimmerman, Steven C.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Organic
Language
eng
Abstract
Part II details cross linking of glycerol dendrimers using the ring closing metathesis (RCM) reaction. An iteratively cross-linked dendrimer was prepared by RCM of an allylated G-3.5 cross-linked dendrimer and the methodology developed for perfect dendrimers was subsequently applied to hyperbranched polyglycerols. Cross-linked dendrimers displayed phase transfer properties and may be useful in therapeutic and nanotechnological applications.
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