University of Illinois Urbana-Champaign

Palladium-Catalyzed Alkenylsilanol Cross -Coupling Reactions: Method Development and Mechanistic Analysis

Sweis, Ramzi Farah

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https://hdl.handle.net/2142/84140

Description

Title
Palladium-Catalyzed Alkenylsilanol Cross -Coupling Reactions: Method Development and Mechanistic Analysis
Author(s)
Sweis, Ramzi Farah
Issue Date
2004
Doctoral Committee Chair(s)
Denmark, Scott E.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Organic
Language
eng
Abstract
The transmetalation mechanism was examined through the natural abundance 13C NMR kinetic isotope effect (KIE) studies. This provided evidence for either palladium-olefin complexation or a Heck-type carbometalation as the turnover-limiting step for these cross-coupling reactions.
Graduation Semester
2004
Type of Resource
text
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http://hdl.handle.net/2142/84140

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