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https://hdl.handle.net/2142/84107
Description
Title
Tetrathiometallates in Synthesis and Catalysis
Author(s)
Schwarz, Daniel Eugene
Issue Date
2003
Doctoral Committee Chair(s)
Rauchfuss, Thomas B.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Inorganic
Language
eng
Abstract
Finally, Et4N[ReS4] has also been shown to react with isocyanides (MeNC, t-BuNC, CyNC) which add across the S=M=S functionality via a 3+1 cycloaddition process in the presence of S 8 to form Et4N[Re(S)(S4)(S2CNR)]. This type of cycloaddition has not been observed before for metal sulfides.
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