Chiral-Phosphoramide-Catalyzed Enantioselective Allylation Reactions: Mechanistic, Structural and Preparative Studies
Fu, Jiping
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https://hdl.handle.net/2142/84099
Description
Title
Chiral-Phosphoramide-Catalyzed Enantioselective Allylation Reactions: Mechanistic, Structural and Preparative Studies
Author(s)
Fu, Jiping
Issue Date
2003
Doctoral Committee Chair(s)
Denmark, Scott E.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Organic
Language
eng
Abstract
The method of generating chiral Lewis acids with a combination of SiCl 4 and chiral phosphoramides has been applied in the formal hetero-Diels-Alder reaction and modest to high selectivities have been obtained.
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