University of Illinois Urbana-Champaign

Synthesis and Maldi-Ms Characterization of New Ruthenium Sulfide Clusters

Eckermann, Amanda Lorraine

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Description

Title
Synthesis and Maldi-Ms Characterization of New Ruthenium Sulfide Clusters
Author(s)
Eckermann, Amanda Lorraine
Issue Date
2002
Doctoral Committee Chair(s)
Rauchfuss, Thomas B.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Inorganic
Language
eng
Abstract
Finally, ruthenium sulfide phosphine nitrosyl clusters resulting from the reaction of RuCl3(NO)(P(aryl)3)2 and S(TMS)2 were investigated. The distorted heterocubane Ru4 S4(NO)4(PPh3)3 was crystallographically characterized and a related cluster with formula Ru4S3(NO) 4(PPh3)3, possibly corresponding to a partial heterocubane structure, was identified using MALDI-MS and IR spectroscopy.
Graduation Semester
2002
Type of Resource
text
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http://hdl.handle.net/2142/84067

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