Fabrication and Characterization of Three Dimensional Photonic Crystals Generated by Multibeam Interference Lithography
Chen, Ying-Chieh
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https://hdl.handle.net/2142/82852
Description
Title
Fabrication and Characterization of Three Dimensional Photonic Crystals Generated by Multibeam Interference Lithography
Author(s)
Chen, Ying-Chieh
Issue Date
2009
Doctoral Committee Chair(s)
Braun, Paul V.
Department of Study
Materials Science and Engineering
Discipline
Materials Science and Engineering
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Engineering, Materials Science
Language
eng
Abstract
Multibeam interference lithography is investigated as a manufacturing technique for three-dimensional photonic crystal templates. In this research, optimization of the optical setup and the photoresist initiation system leads to a significant improvement of the optical quality of the crystal, as characterized by normal incidence optical spectroscopy. Theoretical spectra are calculated and demonstrate close agreement with experimental values, indicating that this fabrication process achieves excellent optical quality. X-ray microscopy provides non-destructive inspection of the fabricated crystals at nano-scale resolution. A reconstructed crystal model is generated by computed tomography which allows for comparison to a predicted structure's geometry and optical spectra. Using the polymer crystal as a template, electrodeposition is performed to completely infiltrate the crystal with Cu2O. After polymer removal the inverted Cu2O crystal exhibits a high peak reflectance at the predicted wavelength, indicating the structure is an exact inverse of the template. A conformal growth algorithm is developed for the commonly used chemical vapor deposition infiltration technique to explain growth results and verified experimentally with atomic layer deposition of oxide materials. Finally, a customized chemically amplified positive photoresist system and its processing steps are developed as a route to zero-shrinkage template material for high fidelity patterning of the designed interference patterns.
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