Temperature -Programmed Desorption Studies on Methanol, Benzene, and Hexafluoroacetylacetone on (2X1)pt(110)
Thomas, Fred Stuart
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https://hdl.handle.net/2142/82483
Description
Title
Temperature -Programmed Desorption Studies on Methanol, Benzene, and Hexafluoroacetylacetone on (2X1)pt(110)
Author(s)
Thomas, Fred Stuart
Issue Date
2000
Doctoral Committee Chair(s)
Masel, Richard I.
Department of Study
Chemical Engineering
Discipline
Chemical Engineering
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Engineering, Chemical
Language
eng
Abstract
TPD was used to study the chemistry of hexafluoroacetylacetone (Hhfac) on oxygen-precovered (2x1)Pt(110). It begins to decompose at 350 K and no platinum is chelated away. Water, carbon monoxide, carbon dioxide, a carbonaceous deposit, and fluorocarbons are the decomposition products. Hhfac is thus not a suitable etchant for platinum.
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