Waveguide chipred-pulse fourier transform microwave spectroscopy of allyl bromide

Permalink

https://hdl.handle.net/2142/51006

Title: Waveguide chipred-pulse fourier transform microwave spectroscopy of allyl bromide
Author(s): McCabe, Morgan N.
Contributor(s): Shipman, Steven
Issue Date: 2014-06-19
Keyword(s): Chirped pulse
Abstract: The rotational spectrum of allyl bromide was recorded from 8.7 to 26.5 GHz at -20 $^{\circ}$C with a waveguide chirped-pulse Fourier transform microwave spectrometer. The rotational spectrum of allyl bromide has been previously studied by Niide and coworkers. \footnote{Y.~Niide,~M,~Takano,T.~Satoh,~and Y.~Sasada~J.~Mol. Spectrosc., 63, 108(1976)}$^,$\footnote {Niide,~Yuzuru, J. Sci. Hiroshima Univ., Ser. A, 48, 1(1984)} However, previous assignments of this spectrum only extended to J = 12 and K$_a$ = 1. Newly acquired data from our spectrometer has allowed us to extend the previous work to higher values of J and K$_a$, leading to significant improvements in the distortion constants in particular. Comparisons between the spectra and conformational preferences of the allyl halides will also be discussed.
Publisher: International Symposium on Molecular Spectroscopy
Type of Resource: text
Language: English
Permalink: http://hdl.handle.net/2142/51006
DOI: https://doi.org/10.15278/isms.2014.RE09
Copyright and License Information: Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/