University of Illinois Urbana-Champaign

The Rotational Spectra, Structures, And Chlorine Nuclear Electric Quadrupole Coupling Constants For A Family Of Three Halogenated Cyclic Alkenes, Cnf2n���4cl2: N = 4, 5, And 6

Long, B.E.

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https://hdl.handle.net/2142/50815

Description

Title
The Rotational Spectra, Structures, And Chlorine Nuclear Electric Quadrupole Coupling Constants For A Family Of Three Halogenated Cyclic Alkenes, Cnf2n���4cl2: N = 4, 5, And 6
Author(s)
Long, B.E.
Contributor(s)
  • Cooke, S.A.
  • Hansen, Lucas
  • Arsenault, E.A.
Issue Date
2014-06-19
Keyword(s)
Chirped pulse
Abstract
Microwave spectra for a family of three halogenated cyclic alkenes, C$_n$F$_{2n-4}$Cl$_2$; n = 4, 5, and 6, have been observed and analyzed. Rotational constants, quartic centrifugal distortion constants, and nuclear electric quadrupole coupling constants for a total of 9 isotopologues have been reported. These molecules are near oblate tops containing two quadrupolar nuclei. Data was first obtained via a chirp pulse Fourier transform microwave (FTMW) spectrometer, and then further analyzed with a Balle-Flygare type FTMW spectrometer to determine the chlorine nuclear electric quadrupole coupling constants. The spectroscopic parameters for all 9 species will be presented and compared.
Publisher
International Symposium on Molecular Spectroscopy
Type of Resource
text
Language
English
Permalink
http://hdl.handle.net/2142/50815
DOI
https://doi.org/10.15278/isms.2014.RE11
Copyright and License Information
Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/

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Abstracts & Presentations - 2014 International Symposium on Molecular Spectroscopy PRIMARY