University of Illinois Urbana-Champaign

Monitoring The Reaction Products Of Perfluoropropionic Acid And Allyl Phenyl Ether Using Chirped-pulse Fourier Transform Microwave (cp-ftmw) Spectroscopy

Frank, Derek S.

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https://hdl.handle.net/2142/50822

Description

Title
Monitoring The Reaction Products Of Perfluoropropionic Acid And Allyl Phenyl Ether Using Chirped-pulse Fourier Transform Microwave (cp-ftmw) Spectroscopy
Author(s)
Frank, Derek S.
Contributor(s)
  • Grubbs, G.S., II
  • Cooke, S.A.
  • Novick, Stewart E.
  • Lin, Wei
  • Obenchain, Daniel A.
Issue Date
2014-06-20
Keyword(s)
Chirped pulse
Abstract
The pure rotational spectra of the reaction mixture of perfluoropropionic acid, CF$_{3}$CF$_{2}$COOH, and allyl phenyl ether, C$_{6}$H$_{5}$OCH$_{2}$CH=CH$_{2}$, have been studied by a pulsed nozzle, chirped-pulse Fourier transform microwave spectrometer in the frequency range of 8-14 GHz. Transitions corresponding to multiple species, two of which being starting materials allyl phenyl ether and perfluoropropionic acid, have been observed and analyzed. Determination of the reaction products was carried out by matching observed rotational constants with ab initio quantum chemical calculations of predicted products and will be discussed. Rotational constants, centrifugal distortion constants and the assignment of allyl phenyl ether and reaction products spectra will all be discussed.
Publisher
International Symposium on Molecular Spectroscopy
Type of Resource
text
Language
English
Permalink
http://hdl.handle.net/2142/50822
DOI
https://doi.org/10.15278/isms.2014.FD01
Copyright and License Information
Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/

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Abstracts & Presentations - 2014 International Symposium on Molecular Spectroscopy PRIMARY