Stark And Zeeman Effect Study Of The [18.6]3.5 - X(1)4.5 Band Of Uranium Monofluoride, Uf.

Linton, Colan

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https://hdl.handle.net/2142/50790 Copy

Description

Title

Stark And Zeeman Effect Study Of The [18.6]3.5 - X(1)4.5 Band Of Uranium Monofluoride, Uf.

Author(s)

Linton, Colan

Contributor(s)

• Steimle, Timothy
• Adam, Allan G.

Issue Date

2014-06-16

Keyword(s)

Small molecules

Abstract

A high resolution spectrum of the [18.6]3.5 - X(1)4.5 band of UF was obtained using the laser ablation specrometer at Arizona State University (ASU). The rotational structure showed significant perturbations in the upper state. Examination of the Stark and Zeeman splittings of the lowest J lines in electric fields up to 3.4 kV/cm and a magnetic field of 1650 Gauss yielded permanent electric dipole moments, $\mu$$_{e}$, of 1.99 and 1.87 Debye and magnetic g-factors, g$_{e}$ of 3.28 and 3.26 for the ground and excited states respectively. The above experimental results will be discussed in terms of the configurational composition of the ground and excited states and compared with recent theoretical calculations\footnote{Ivan O. Antonov and Michael C. Heaven, J. Phys. Chem. A 2013, 117, 9684-9694}.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

text

Language

English

Permalink

http://hdl.handle.net/2142/50790

DOI

https://doi.org/10.15278/isms.2014.MG08

Copyright and License Information

Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/

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