University of Illinois Urbana-Champaign

Vibrational states at the dissociation limit protected from vibrational energy flow

Gruebele, Martin

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https://hdl.handle.net/2142/55878

Description

Title
Vibrational states at the dissociation limit protected from vibrational energy flow
Author(s)
Gruebele, Martin
Issue Date
2014-06-16
Keyword(s)
Mini-symposium: Spectroscopy in Kinetics and Dynamics
Date of Ingest
  • 2014-11-21T22:50:38Z
  • 2015-04-14T18:39:28Z
Abstract
I will discuss the detection of sharp vibrational transitions with up to 40 quanta of total excitation above the dissociation limit of thiophosgene (SCCl$_2$). A 6-D CASSCF calculation and filtered diagonalization of eigenstates to compute dilution factors for bright states explains the 'survival' of these states and their expected number quantitatively.
Publisher
International Symposium on Molecular Spectroscopy
Type of Resource
text
Genre of Resource
Conference Paper / Presentation
Language
en
Permalink
http://hdl.handle.net/2142/55878
DOI
https://doi.org/10.15278/isms.2014.MH07
Copyright and License Information
Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/

Owning Collections

Abstracts & Presentations - 2014 International Symposium on Molecular Spectroscopy PRIMARY