Application of two dimensional flourescence spectroscopy to transition metal clusters

Kokkin, Damian L

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https://hdl.handle.net/2142/50986 Copy

Description

Title

Application of two dimensional flourescence spectroscopy to transition metal clusters

Author(s)

Kokkin, Damian L

Contributor(s)

Steimle, Timothy

Issue Date

2014-06-17

Keyword(s)

Metal containing

Abstract

\begin{wrapfigure}{r}{0pt} \includegraphics[scale=0.9]{NiONiO2.eps} \end{wrapfigure} Determining the physical properties (bond lengths, angles, dipole moments, etc) of transition metal oxides and dioxides is relevant to catalysis, high temperature chemistry, materials science and astrophysics. Analysis of optical spectra is a convenient method for extraction of physical properties, but can be difficult because of the density of electronic states and in the case of the dioxides, presence of both the oxide and superoxide forms. Here we demonstrate the application of two dimensional fluorescence spectroscopy\footnote{N.J. Reilly, T.W. Schmidt, S.H. Kable, \textit{J. Phys. Chem. A.}, 110(45), 12355-12359, 2006} for aiding in the assignment and analysis. Particular attention will be paid to the spectroscopy of first row transition metal monoxides and dioxides of Nickel, NiO and NiO$_2$, and Manganese, MnO. Furthermore, the application of this technique to discovering the spectrum of other transition metal systems such as Metal-dicarbides will be outlined.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

text

Language

English

Permalink

http://hdl.handle.net/2142/50986

DOI

https://doi.org/10.15278/isms.2014.TK12

Copyright and License Information

Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/

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