University of Illinois Urbana-Champaign

Chirped-pulse Fourier Transform Microwave Spectroscopy Of 2-chloro-3-fluoropyridine And 2-chloro-6-fluoropyridine

Brown, Gordon

Content Files
RE12_Abstract.pdf
RE12_Abstract.txt
RE12_Presentation.pptx

Permalink

https://hdl.handle.net/2142/50776

Description

Title
Chirped-pulse Fourier Transform Microwave Spectroscopy Of 2-chloro-3-fluoropyridine And 2-chloro-6-fluoropyridine
Author(s)
Brown, Gordon
Contributor(s)
  • Chewning, J. Chase
  • Arnold, Sean
Issue Date
2014-06-19
Keyword(s)
Chirped pulse
Date of Ingest
  • 2014-09-17T16:54:48Z
  • 2015-04-14T18:37:29Z
Abstract
The pure rotational spectra of 2-chloro-3-fluoropyridine and 2-chloro-6-fluoropyridine were measured on a chirped-pulsed Fourier transform microwave (CP-FTMW) spectrometer in the 8 – 18.5 GHz frequency range. The spectra were analyzed to find the rotational constants of the molecules for both the \textsuperscript{35}Cl and the \textsuperscript{37}Cl isotopologues. The measured rotational transitions exhibit hyperfine splitting, from which the nuclear quadrupole coupling constants have been assigned. The rotational constants and the nuclear quadrupole coupling constants have been compared to \emph{ab initio} calculations performed using the Gaussian 03W software package.
Publisher
International Symposium on Molecular Spectroscopy
Type of Resource
text
Genre of Resource
Conference Paper / Presentation
Language
English
Permalink
http://hdl.handle.net/2142/50776
DOI
https://doi.org/10.15278/isms.2014.RE12
Copyright and License Information
Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/

Owning Collections

Abstracts & Presentations - 2014 International Symposium on Molecular Spectroscopy PRIMARY