Preparation and Chemiluminescence of Cyclopropyl-Substituted Malonyl Peroxides
Darmon, Michael John
This item is only available for download by members of the University of Illinois community. Students, faculty, and staff at the U of I may log in with your NetID and password to view the item. If you are trying to access an Illinois-restricted dissertation or thesis, you can request a copy through your library's Inter-Library Loan office or purchase a copy directly from ProQuest.
Permalink
https://hdl.handle.net/2142/70187
Description
Title
Preparation and Chemiluminescence of Cyclopropyl-Substituted Malonyl Peroxides
Author(s)
Darmon, Michael John
Issue Date
1982
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Organic
Abstract
4-Spiro{(2'-spirocyclopropyl)-cyclohexyl}-1,2-dioxolane-3,5-dione (2) and 4-cyclopropyl-4-methyl-1,2-dioxolane-3,5-dione (1) are prepared by the reaction of dicyclohexylcarbodiimide and hydrogen peroxide with the parent malonic acids. Chemiluminescence is observed when the cyclopropyl-substituted malonyl peroxides, 1 and 2, are heated in the presence of added aromatic fluorescers. The chemiluminescence is explained by the activated CIEEL mechanism with the aromatic fluorescer and malonyl peroxide. A cyclopropylcarbinyl-allylcarbinyl radical rearrangement is proposed to be involved in the chemiluminescence mechanism.
Use this login method if you
don't
have an
@illinois.edu
email address.
(Oops, I do have one)
IDEALS migrated to a new platform on June 23, 2022. If you created
your account prior to this date, you will have to reset your password
using the forgot-password link below.
