Calorimetry and Structure-Reactivity Relationships in Hypervalent Compounds of Phosphorus and Sulfur
Ross, Michael Reiff
This item is only available for download by members of the University of Illinois community. Students, faculty, and staff at the U of I may log in with your NetID and password to view the item. If you are trying to access an Illinois-restricted dissertation or thesis, you can request a copy through your library's Inter-Library Loan office or purchase a copy directly from ProQuest.
Permalink
https://hdl.handle.net/2142/70169
Description
Title
Calorimetry and Structure-Reactivity Relationships in Hypervalent Compounds of Phosphorus and Sulfur
Author(s)
Ross, Michael Reiff
Issue Date
1981
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Organic
Abstract
Phosphoranoxide 1, or its conjugate acid (10), TBP 10-P-5 species, hydrolyze to diol phosphinate 11 in boiling ethanolic KOH (72 hours); this reaction is reversed by treating 11 with aqueous HCl. Under these conditions, hydrolysis of isoelectronic-isostructural 10-S-5 sulfurane oxide 2b gave n
Use this login method if you
don't
have an
@illinois.edu
email address.
(Oops, I do have one)
IDEALS migrated to a new platform on June 23, 2022. If you created
your account prior to this date, you will have to reset your password
using the forgot-password link below.
