Mid-infrared Spectrum Of The Atmospherically Significant N2-h2o Complex

Bevan, John W.

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https://hdl.handle.net/2142/50868 Copy

Description

Title

Mid-infrared Spectrum Of The Atmospherically Significant N2-h2o Complex

Author(s)

Bevan, John W.

Contributor(s)

• Coudert, L.H.
• Lucchese, Robert R.
• McElmurry, Blake A.
• Springer, Sean D.

Issue Date

2014-06-20

Keyword(s)

Clusters/Complexes

Abstract

Rovibrational transitions associated with tunneling states in the vibration of the N$_{2}$--H$_{2}$O complex have been recorded using a supersonic jet quantum cascade laser spectrometer at 6.2$\mu$m. Analysis of the resulting spectra is facilitated by incorporating fits of previously recorded microwave and submillimeter data accounting for Coriolis coupling to obtain the levels of the ground vibrational state. The results are then used to confirm assignment of the \nub{3} vibration and explore the nature of tunneling dynamics in associated vibrationally excited states of the complex.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

text

Language

English

Permalink

http://hdl.handle.net/2142/50868

Copyright and License Information

Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/

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