Orientational order and finite strain in nematic elastomers
Fried, Eliot; Sellers, Shaun
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https://hdl.handle.net/2142/324
Description
Title
Orientational order and finite strain in nematic elastomers
Author(s)
Fried, Eliot
Sellers, Shaun
Issue Date
2005-05
Abstract
Nematic elastomers exhibit large, spontaneous shape changes at the transition from the high-temperature isotropic phase to the low-temperature nematic phase. These finite deformations are studied here in the context of a nonlinear, properly invariant, variational theory that couples the orientational order and elastic deformation. The theory is based on the minimization of a free-energy functional that consists of two contributions: a nematic one due to the interaction of the mesogenic units and an elastic one arising from the stretching of the cross-linked polymer chains. Suitable choices for these two contributions allow for large, reversible, spontaneous shape changes in which the elastic deformation can affect the isotropic–nematic transition temperature. The change in transition temperature as well as the magnitude of the resulting spontaneous deformation are illustrated for various parameter values. The theory includes soft elasticity as a special case but is not restricted to it.
Publisher
Department of Theoretical and Applied Mechanics (UIUC)
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