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https://hdl.handle.net/2142/25744
Description
Title
Polaron transport in ionic crystals
Author(s)
Borders, James Alan
Issue Date
1968
Doctoral Committee Chair(s)
Brown, Frederick C.
Department of Study
Physics
Discipline
Physics
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
polaron transport
ionic crystals
highly insulating photoconductors
space charge polarization
Language
en
Abstract
A new technique was developed for making measurements on highly
insulating photoconductors. This technique features ease of data
reduction, relative freedom from space charge polarization, and higher
sensitivity and stability than that of previous designs. Using the new
method, measurements were made of Hall effect, hot electron effects and
magnetoconductivity in a variety of ionic crystals. The conduction bands
of seven alkali halides were found to be isotropic with a measuring
accuracy of ± 0.5%.
Cyclotron resonance of photocarriers was observed at 139 GHz by
electron heating effects. Polaron effective masses were measured in a
variety of materials and the results compared with previous experiments
and theory. In addition, transport effects due to spin polarization were
qualitatively identified in colored potassium halides. These effects
have been attributed to spin polarization of the F centers along with the
conduction electrons. They have been analyzed using a simplified model.
Preliminary measurements of spectral response of photoconductivity
in AgBr have been made and the results compared with optical absorption.
Structure has been found which may be related to the presence of minute
traces of impurity such as iodine.
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