Low temperature, glass-like properties of crystalline beta-alumina
Anthony, Philip John
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https://hdl.handle.net/2142/25584
Description
Title
Low temperature, glass-like properties of crystalline beta-alumina
Author(s)
Anthony, Philip John
Issue Date
1978
Doctoral Committee Chair(s)
Anderson, A.C.
Department of Study
Physics
Discipline
Physics
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
glass-like properties
crystalline beta-alumina
low temperature properties
single crystals
amorphous materials
Language
en
Abstract
The low temperature properties measured for single crystal Na, Ag, K, and Li B-alumina are characteristic of those found in amorphous materials. The specific heat is dominated below 1 K by a term approximately linear in temperature instead of the cubic dependence normal for crystals. All except K B-alumina have an approximately quadratically temperature dependent thermal conductivity below 1 K and a nearly temperature independent thermal conductivity near 10 K. Both features are associated with glassy materials,
while pure cryst~lline dielectrics have thermal conductivities cubic in
temperature. The dielectric susceptibilities of the B-aluminas vary a few parts in 102 over three orders of magnitude in temperature, with the dependences
again of the same form as those found in glasses. Unlike glasses, however, the variations of susceptibility for all but Li J3-alumina are found
to be extremely anisotropic. The magnitudes of the measured properties are dependent on the species of metal ion present.
Beta-alumina is a layered crystal composed of slabs of alumina separated by non-stoichiometrically occupied planes containing the monovalent cations in a disordered environment. The glass-like properties measured indicate that there is present in the Beta-aluminas a broad band of low energy excitations associated with the cations in the planes. The tunneling-states model, which explains glassy properties with excitations arising from quantum
mechanical tunneling of units in double-well potentials, was used to analyze the data. An energy dependent density of tunneling states with a spectrum of relaxation times for each tunneling-state energy was found to be necessary to explain the properties of glasses and the B-aluminas.
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