MEASUREMENTS OF VIBRATIONALLY EXCITED OXYGEN MOLECULES IN PREHEATED O₂-Ar MIXTURES EXCITED BY A NANOSECOND PULSE DISCHAGE

Orr, Keegan

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https://hdl.handle.net/2142/122717 Copy

Description

Title

MEASUREMENTS OF VIBRATIONALLY EXCITED OXYGEN MOLECULES IN PREHEATED O₂-Ar MIXTURES EXCITED BY A NANOSECOND PULSE DISCHAGE

Author(s)

Orr, Keegan

Contributor(s)

• Adamovich, Igor V.
• Esposito, Fabrizio
• Armenise, Iole
• Van den Bekerom, Dirk

Issue Date

2023-06-21

Keyword(s)

Instrument/Technique Demonstration

Abstract

Kinetics of O₂ vibrational excitation is studied during the O atom recombination in an O₂-Ar mixture partially dis- sociated by a burst of ns discharge pulses in a heated flow reactor at T=400-800 K and P=200-600 Torr. Time-resolved vibrational level populations of molecular oxygen in the ground electronic state, O₂(v=8-13,17-20), are measured by ps Laser Induced Fluorescence on the O₂ Schumann Runge bands, with absolute calibration by NO LIF in a NO-N₂ mixture with a known composition, at quenching-free conditions. O atom number density in the same mixture is measured by ps Two-Photon absorption LIF (TALIF). The discharge generates a diffuse volumetric plasma, without well-pronounced filaments. The results indicate a rapid initial decay of the O₂(X,v=8-20) molecules generated by electron impact in the discharge, on 20 µs time scale, due to the V-V exchange and V-T relaxation. This decay is followed by a much slower decay, on the time scale much longer compared to the characteristic time for V-V relaxation, 1 ms. This indicates an additional process of O₂(v) generation by chemical reactions initiated by the O atom recombination and possibly ozone chemistry. Comparison of the experimental data with the master equation kinetic modeling predictions is used to infer the state-specific rates of chemical reactions generating vibrationally excited O₂.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

Text

Language

eng

Handle URL

https://hdl.handle.net/2142/122717

DOI

https://doi.org/10.15278/isms.2023.7350

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