RESOLVING ISOMERS OF COPPER TRIOXIDE ANION VIA TEMPERATURE DEPENDENT PHOTOELECTRON IMAGING
Kocheril, G. Stephen
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https://hdl.handle.net/2142/122658
Description
Title
RESOLVING ISOMERS OF COPPER TRIOXIDE ANION VIA TEMPERATURE DEPENDENT PHOTOELECTRON IMAGING
Author(s)
Kocheril, G. Stephen
Contributor(s)
Wang, Lai-Sheng
Gao, Han-Wen
Issue Date
2023-06-19
Keyword(s)
Mini-symposium: Spectroscopy with Cryogenic Ion Traps
Abstract
Although the photoelectron spectrum of copper trioxide was first reported in the late 1990’s, it has remained unassigned to date. Several calculations have predicted the presence of multiple isomers, but the complexity of the system has prevented any assignment of the experimental spectrum. We have revisited the photoelectron spectrum of copper trioxide, now with high-resolution photoelectron imaging and a cryogenically-cooled ion trap. The new temperature dependent photoelectron spectra have resolved the presence of two distinct isomers, allowing for the full assignment of the photoelectron spectrum of copper trioxide for the first time.
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